Simulation of Multifilament Semicrystalline Polymer Fiber Melt-Spinning
نویسندگان
چکیده
The goal of this effort is to provide an accurate simulation of multifilament fiber melt spinning, applicable for a wide range of material and process conditions. For ease of use, the model should run on a standard laptop or desktop computer in reasonable time (one hour or less). Most melt spinning models simulate the formation of a single filament, with little or no attention given to multifilament effects. Available multifilament simulations are primarily limited to Newtonian constitutive models for the polymer flow. We present a multifilament simulation based on the flow-enhanced crystallization approach of Shrikhande et al. [J. Appl. Polym. Sci., 100, 2006, 3240-3254] combined with a variant on the multifilament quench model of Zhang, et al. [J. Macromol. Sci. Phys., 47, 2007, 793-806]. We demonstrate the versatility of this model by applying it to isotactic polypropylene and polyethylene terephthalate, under a variety of process conditions.
منابع مشابه
In-Situ X-Ray Characterization of Fiber Structure During Melt Spinning
The properties of a polymer are strongly influenced by its morphology. In the case of fibers from semicrystalline polymers this consists of the degree of crystallinity, the spacing and alignment of the crystalline regions, and molecular orientation of the polymer chains in the amorphous regions. Information on crystallinity and orientation can be obtained from X-ray analysis. In-situ X-ray char...
متن کاملRedistribution of Fibers in the Structure of Hollow Ring Spun Yarn
Core yarn was spun by introducing a PVA multifilament as the core through the yarn forming zone of a ring spinning frame and viscose fibers as the sheath containing tracer fibers. The water soluble PVA multifilament was extracted from the yarn structure. Then internal structure and properties of the hollow ring yarn was assessed and compared with those of typical ring yarns. Also, two plain fab...
متن کاملBioactive Nano-Composite Multifilament Yarns
Physical, mechanical and antimicrobial properties of nylon 6 (polycaprolactam) doped with different amounts of silver nanoparticles were investigated in this study. Two series of filament yarns counts (20 and 70 Denier) were produced by melt spinning method with different amounts of silver nanoparticles contents (0, 0.5, 1 and 4 wt%). Elemental analysis of silver and titanium dioxide (present i...
متن کاملOptimal Control of Melt Spinning Processes
An optimal control problem for a mathematical model of a melt spinning process is considered. Newtonian and non–Newtonian models are used to describe the rheology of the polymeric material, the fiber is made of. The extrusion velocity of the polymer at the spinneret as well as the velocity and temperature of the quench air serve as control variables. A constrained optimization problem is derive...
متن کاملModel Study of the Spinning of Thermotropic Liquid Crystalline Polymers: Fiber Performance Predictions and Bounds on Throughput
We apply a model for thermotropic liquid crystalline polymers (TLCPs) that couples hydrodynamics, anisotropic rodlike microstructural dynamics, free surface effects, and thermodynamics to study fiber spinning of these materials. The model incorporates a Doi type theory for the nematodynamics, along with physical constants, empirical correlations for air drag and functional heat loss coefficient...
متن کامل